Optimise is a unique Limit Break for the Warrior that is learned by performing the Robot Technique workout during the Warrior episode of the Reunion DLC. It grants three stacks of Re-Equip Next, which means your next three pieces of equipment used can be used again. This can let you use a piece of equipment four times, which is useful to gain control of your dice using Bicep Curl.

The only way to get Optimise is to complete this workout:

• Robot Technique